Hershey's Unsweetened Cocoa makes me anxious.
Raw Cacao does not make me anxious. Or so it seems.
Does one have caffeine and the other not, or do they both contain caffeine?
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Contrary to what most people believe, chocolate does not contain a significant amount of caffeine - about 2mg/g. It does however contain more theobromine - about 15mg/g. Both chemicals are xanthines, and many xanthines are stimulants.
Summary: both contain small amounts of caffeine.