I use pure sunflower and jojoba oils on my skin, and Living Proof brand shampoo and conditioner (and regular, high quality styling products, used minimally). For my face I use both Weleda's Cold Cream and Green Pasture Beauty Balm. I ADORE Weleda's skin food hand creme. Most of my makeup is Bare Escentuals brand, but I wear makeup once every two weeks so I don't really sweat it - I use what I love and collect Sephora points along the way.
Arm & Hammer unscented baking soda deodorant and in the summer only when necessary, traditional Secret antiperspirent (maybe 3 x week during July & August), especially at work (high end hotel). The crystals and other alternatives have never worked for me. Tom's toothpaste.
I have really dry skin/hair and live in a dry climate, so I'm first concerned about products that work/keep me itch-free, then from there I try to get as healthy as possible. If I need sunscreen (at 9000' in Colorado, sometimes you really do need it) I use Blue Lizard.
Oh, and gorgeous OPI nail polish. Being sexy is primal.